Unusual KIE and dynamics effects in the Fe-catalyzed hetero-Diels-Alder reaction of unactivated aldehydes and dienes
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DOI: 10.1038/s41467-020-15599-w
Abstract: Hetero-Diels-Alder (HDA) reaction is an important synthetic method for many natural products. An iron(III) catalyst was developed to catalyze the challenging HDA reaction of unactivated aldehydes and dienes with high selectivity. Here we report extensive density-functional… read more here.
Keywords: diels alder; kie; hetero diels; unactivated aldehydes ... See more keywords