Dicarbofunctionalizations of an Unactivated Alkene via Photoredox/Nickel Dual Catalysis.
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DOI: 10.1021/acs.orglett.2c02355
Abstract: 1,2-Dicarbofunctionalization of unactivated olefin has been reported under photoredox/nickel dual catalysis. The mildness of the visible-light-mediated reaction allows the use of various alkyl and aryl electrophiles with several sensitive functional groups. The protocol was equally… read more here.
Keywords: unactivated alkene; dicarbofunctionalizations unactivated; dual catalysis; photoredox nickel ... See more keywords
A Visible-Light Organophotoredox-Catalyzed anti-Markovnikov Hydrocarbamoylation of Unactivated Alkene and Cyclization Cascade via Radical Relay.
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DOI: 10.1021/acs.orglett.5c02878
Abstract: An organophotoredox-catalyzed anti-Markovnikov addition of the carbamoyl radical generated through the homolytic cleavage of 4-carbamoyl-1,4-dihydropyridine to the challenging unactivated alkene has been developed. Interestingly, the amino acid-derived carbamoyl precursor provided a unique opportunity for N-terminus… read more here.
Keywords: anti markovnikov; catalyzed anti; organophotoredox catalyzed; radical relay ... See more keywords