Rhodium-Catalyzed Carbonylative Synthesis of Aryl Salicylates from Unactivated Phenols.
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DOI: 10.1021/acs.orglett.0c02133
Abstract: A rhodium-catalyzed carbonylative transformation of unactivated phenols to aryl salicylates is described. This protocol is characterized by utilizing 1,3-rhodium migration as the key step to provide direct access to synthesize o-hydroxyaryl esters. Various desired aryl… read more here.
Keywords: unactivated phenols; rhodium catalyzed; carbonylative synthesis; aryl salicylates ... See more keywords