Cu-Catalyzed C(sp3) Amination of Unactivated Secondary Alkyl Iodides Promoted by Diaryliodonium Salts.
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DOI: 10.1021/acs.orglett.3c01216
Abstract: Herein, we describe the development of a copper-catalyzed C(sp3) amination of unactivated secondary alkyl iodides mediated by diaryliodonium salts. Our protocol is enabled by the intermediacy of aryl radical species that undergo halogen atom transfer… read more here.
Keywords: sp3 amination; alkyl iodides; amination unactivated; catalyzed sp3 ... See more keywords