Unexpected Alkene Isomerization during Iterative Cross-Coupling To Form Hindered, Electron-Deficient Trienes.
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DOI: 10.1021/acs.orglett.8b00809
Abstract: An iterative cross-coupling approach to conjugated trienes was explored as part of a planned stereoselective synthesis of bicyclic terpenes. Using a bifunctional bromoboronate building block, sequential Suzuki coupling reactions were employed to provide a conjugated… read more here.
Keywords: iterative cross; cross; alkene isomerization; unexpected alkene ... See more keywords