An unexpected formation of a Ru(III) benzylidene complex during activation of a LatMet-type ring-opening polymerisation catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.05.014
Abstract: Abstract Upon activation with C2Cl6 known latent Ru metathesis catalyst LatMet (13) exhibited activity in RCM and in ROMP of DCPD. A by-product of such activation, an aryloxybenzylidene ruthenium(III) complex 17 have been independently synthesised… read more here.
Keywords: iii benzylidene; formation iii; benzylidene complex; unexpected formation ... See more keywords
Unexpected formation of 1,4-diphenylbutylphosphinic acid from 1,4-diphenylbuta-1,3-diene and elemental phosphorus via the Trofimov–Gusarova reaction
Sign Up to like & getrecommendations! Published in 2017 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2017.03.009
Abstract: trans,trans -1,4-Diphenylbuta-1,3-diene reacts with elemental (red) phosphorus in the superbasic KOH / DMSO (H 2 O) system (120 °C, 3 h) to give, after acidic work-up, 1,4-diphenylbutylphosphinic acid in 48% yield. read more here.
Keywords: diphenylbutylphosphinic acid; formation diphenylbutylphosphinic; phosphorus; diphenylbuta diene ... See more keywords
Unexpected formation of benziphthalocyanine dimer: An easily synthesizable dimer of phthalocyanine analogue
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.04.089
Abstract: Methylene-bridged benziphthalocyanine dimer 2 was unexpectedly generated by the reaction of dihydroxybenziphthalocyanine 1 and formaldehyde in the presence of a catalytic amount of a base at room temperature. Single-crystal X-ray diffraction analysis of 2 revealed… read more here.
Keywords: formation benziphthalocyanine; benziphthalocyanine dimer; dimer; dimer easily ... See more keywords
Unexpected formation of gold nanoflowers by a green synthesis method as agents for a safe and effective photothermal therapy.
Sign Up to like & getrecommendations! Published in 2017 at "Nanoscale"
DOI: 10.1039/c7nr06286a
Abstract: Star fruit (Averrhoa carambola) juice rich in vitamin C and polyphenolic antioxidants was used to synthesize branched gold nanoflowers. These biocompatible and stable gold nanoflowers show strong near-infrared absorption. They are successfully demonstrated to be… read more here.
Keywords: gold nanoflowers; formation gold; unexpected formation; gold ... See more keywords
Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02268g
Abstract: We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant… read more here.
Keywords: coii6cuii6 nanowheel; formation dodecanuclear; coii6cuii6; dodecanuclear coii6cuii6 ... See more keywords
Unexpected formation of polymeric silver(I) complexes of azine-type ligand via self-assembly of Ag-salts with isatin oxamohydrazide
Sign Up to like & getrecommendations! Published in 2018 at "Royal Society Open Science"
DOI: 10.1098/rsos.180434
Abstract: Isatin oxamohydrazide (L) reacted with the aqueous solution of silver nitrate at room temperature afforded the polymeric silver(I) nitrato complex, [Ag2L′(NO3)2]n, (1) of the azine ligand (L′). Similarly, the reaction of L with silver(I) perchlorate… read more here.
Keywords: silver; polymeric silver; isatin oxamohydrazide; reaction ... See more keywords
Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro[2.2]metaparacyclophanes
Sign Up to like & getrecommendations! Published in 2021 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.17.109
Abstract: Substituted [2.2]metaparacyclophanes are amongst the least studied of the simple cyclophanes. This is undoubtedly the result of the lengthy syntheses of these compounds. We report the simple synthesis of a rare example of a non-symmetric… read more here.
Keywords: non symmetric; paracyclophane unexpected; formation non; paracyclophane ... See more keywords