Atmospheric Oxidation of Piperazine Initiated by ·Cl: Unexpected High Nitrosamine Yield.
Sign Up to like & getrecommendations! Published in 2018 at "Environmental science & technology"
DOI: 10.1021/acs.est.8b02510
Abstract: Chlorine radicals (·Cl) initiated amine oxidation plays an important role for the formation of carcinogenic nitrosamine in the atmosphere. Piperazine (PZ) is considered as a potential atmospheric pollutant since it is an alternative solvent to… read more here.
Keywords: oxidation; atmospheric oxidation; yield; unexpected high ... See more keywords
Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)-Ru(III) Dimer Coupling.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01068
Abstract: In this contribution, we report the synthesis and full characterization of the first mixed-valence Ru(II)/Ru(III) ion-pair complex, [RuII(bipy)2(pic)]+[cis-RuIIICl2(pic)2]-, in the solid state and in aqueous solution, where bipy = 2,2'-bipyridine and pic- = picolinate. In… read more here.
Keywords: valence iii; pair complex; iii ion; mixed valence ... See more keywords
Unexpected High-Pressure Phase of GeTe with an Origin of Low Ionicity and Electron Delocalization
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b03984
Abstract: First-principles evolutionary searches have been performed to systematically explore the high-pressure phases of germanium telluride. Two new phases are found to be both energetically and dynamical... read more here.
Keywords: pressure phase; gete origin; high pressure; unexpected high ... See more keywords
A Au monolayer on WC(0001) with unexpected high activity towards CO oxidation.
Sign Up to like & getrecommendations! Published in 2018 at "Nanoscale"
DOI: 10.1039/c7nr09498a
Abstract: Catalysts with weak adsorption yet high reactivity towards CO are urgently required to solve the serious problem of CO poisoning that occurs in many important reactions, e.g., in fuel cells. Using the combination of density… read more here.
Keywords: monolayer; 0001 unexpected; monolayer 0001; high activity ... See more keywords