Sign Up to like & get
recommendations!
0
Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc04558e
Abstract: We have found that cyclic perfluorinated iodanes react with electrophiles (E+ = Br, Cl, F, I) to afford perfluorinated E-RF compounds. This reactivity is unexpected since cyclic perfluorinated iodanes are considered as electrophilic reagents that…
read more here.
Keywords:
perfluorinated iodanes;
cyclic perfluorinated;
unexpected reactivity;
reactivity cyclic ... See more keywords
Sign Up to like & get
recommendations!
2
Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00530e
Abstract: Palladium-catalyzed coupling of 4,5-dibromo-2,7,9,9-tetramethylacridan with two equivalents of 1,3-diisopropylimidazolin-2-imine afforded 4,5-bis(1,3-diisopropylimidazolin-2-imino)-2,7,9,9-tetramethylacridan, H[AII2]. Reaction of the H[AII2] pro-ligand with one equivalent of [M(CH2SiMe3)3(THF)2] (M = Y or Sc) yielded the base-free neutral dialkyl complexes [(AII2)M(CH2SiMe3)2] {M…
read more here.
Keywords:
dialkyl complexes;
unexpected reactivity;
cph3;
ligand ... See more keywords