Unexpected B/Al Transelementation within a Rh Pincer Complex.
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DOI: 10.1021/jacs.0c09344
Abstract: We report the synthesis of PAlP and PBP pincer complexes of Rh with a central bis(N-pyrrolyl)aluminyl or -boryl unit. Complex (PAlpyP)Rh(CO)2 possesses an aluminyl site stabilized by coordination of pyridine, resulting in a four-coordinate Al.… read more here.
Keywords: pincer; pincer complex; unexpected transelementation; within pincer ... See more keywords