Unified strategy of supermesh generation for planar, cylindrical, and spherical non-conformal interfaces by using 2-D intersection algorithm
Sign Up to like & getrecommendations! Published in 2021 at "Applied Mathematical Modelling"
DOI: 10.1016/j.apm.2021.01.043
Abstract: Abstract Aimed at decreasing the complexity of calculating the intersection of a pair of overlapped interfaces, this paper presents an efficient unified strategy to generate a supermesh for planar, cylindrical, and spherical non-conformal interfaces uniquely,… read more here.
Keywords: planar cylindrical; cylindrical spherical; unified strategy; spherical non ... See more keywords
SuFEx Activation with Ca(NTf2)2: A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides
Sign Up to like & getrecommendations! Published in 2020 at "Organic Letters"
DOI: 10.1021/acs.orglett.0c01397
Abstract: A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a diverse set of sulfamides, sulfamates, and sulfonamides at… read more here.
Keywords: unified strategy; sulfamates sulfonamides; activation ntf2; sulfamides sulfamates ... See more keywords
A Chiral Pentenolide-Based Unified Strategy toward Dihydrocorynantheal, Dihydrocorynantheol, Protoemetine, Protoemetinol, and Yohimbane.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b01573
Abstract: An organocatalytic cross-aldol reaction of formaldehyde (formalin) with alkyl aldehydes, followed by the Z-selective Horner-Wadsworth-Emmons (HWE) reaction and immediate lactonization, afforded γ-alkylated pentenolides in good overall yields and excellent enantioselectivities. Based on this scalable sequence,… read more here.
Keywords: unified strategy; toward dihydrocorynantheal; pentenolide based; based unified ... See more keywords
Copper-Catalyzed Asymmetric Conjugate Additions of Bis(pinacolato)diboron and Dimethylzinc to Acyl- N-methylimidazole Michael Acceptors: A Highly Stereoselective Unified Strategy for 1,3,5,... n (OH, Me) Motif Synthesis.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00479
Abstract: A unified strategy for the construction of prevalent 1,3,5,... n (OH, Me) motifs based on consecutive copper-catalyzed asymmetric conjugate borylation (ACB) and methylation (ACA) reactions involving α,β-unsaturated 2-acyl- N-methylimidazoles is described. Good yields and high… read more here.
Keywords: catalyzed asymmetric; asymmetric conjugate; unified strategy; copper catalyzed ... See more keywords
A Unified Strategy for the Synthesis of Difluoromethyl- and Vinylfluoride-Containing Scaffolds.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02887
Abstract: Here, we report a general method for the synthesis of quaternary and tertiary difluoromethylated compounds and their vinylfluoride analogues. The strategy, which relies on a two-step sequence featuring a C-selective electrophilic difluoromethylation and either a… read more here.
Keywords: unified strategy; strategy synthesis; difluoromethyl vinylfluoride; synthesis difluoromethyl ... See more keywords
A unified strategy for the total syntheses of eribulin and a macrolactam analogue of halichondrin B
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2208938119
Abstract: Significance More than 20 years have passed since the first total synthesis of eribulin was reported, and numerous attempts thereafter failed to reach the final target; a unified strategy for the total syntheses of eribulin… read more here.
Keywords: total syntheses; syntheses eribulin; unified strategy; macrolactam analogue ... See more keywords