A Unique Fe–N4 Coordination System Enabling Transformation of Oxygen into Superoxide for Photocatalytic CH Activation with High Efficiency and Selectivity
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202200612
Abstract: Selective oxidation of CH bonds is one of the most important reactions in organic synthesis. However, activation of the α‐CH bond of ethylbenzene by use of photocatalysis‐generated superoxide anions (O2•−) remains a challenge. Herein, the… read more here.
Keywords: system; unique coordination; coordination system; oxygen ... See more keywords
[38]Octaphyrin bis-Sn(IV) complexes with unique coordination geometries
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Porphyrins and Phthalocyanines"
DOI: 10.1142/s1088424621500103
Abstract: Metal complexation of octaphyrin(1.1.1.1.1.1.1.1) triggers unique ring-fixation aptitudes or unexpected rearrangement (cleavage) reactions. In this paper, a unique complexation behavior of [38]octa... read more here.
Keywords: complexes unique; coordination geometries; bis complexes; unique coordination ... See more keywords