Light-Induced RAFT Single Unit Monomer Insertion in Aqueous Solution-Toward Sequence-Controlled Polymers.
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201800240
Abstract: First report on the sequential, visible light-initiated, single unit monomer insertion (SUMI) of N,N-dimethylacrylamide (DMAm) into the reversible addition fragmentation chain transfer (RAFT) agent, 4-((((2-carboxyethyl)thio)carbonothioyl)thio)-4-cyanopentanoic acid (CTA1 ), in aqueous solution is provided. The specificity… read more here.
Keywords: monomer insertion; single unit; light; aqueous solution ... See more keywords
PET-RAFT single unit monomer insertion of β-methylstyrene derivatives: RAFT degradation and reaction selectivity.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc03927j
Abstract: Reversible addition-fragmentation chain transfer (RAFT) single unit monomer insertion (SUMI) of β-methylstyrene derivatives into diverse RAFT agents presented fast reaction kinetics, but significant degradation of the SUMI products occurred due to a hydrogen abstraction reaction.… read more here.
Keywords: degradation; raft single; raft; single unit ... See more keywords