Synthesis of derivatives of podocarpane-type diterpenoids through Diels-Alder cycloaddition and photo-decarbonylation from unmasked ortho-benzoquinone
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DOI: 10.1016/j.tet.2017.02.032
Abstract: Derivatives of podocarpane-type diterpenoids, including cassane-type, abietane-type and totarane-type diterpenoids, are either widely distributed natural products or common intermediates in synthetic and medicinal chemistry. Although unmasked ortho-benzoquinone has been used in [4+2] cycloadditions in sparse… read more here.
Keywords: unmasked ortho; ortho benzoquinone; type diterpenoids; podocarpane type ... See more keywords