Syntheses, structural diversity, magnetic properties and dye absorption of various Co(II) MOFs based on a semi-flexible 4-(3,5-dicarboxylatobenzyloxy)benzoic acid
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DOI: 10.1039/c7ce01229b
Abstract: Five novel Co(II) metal–organic frameworks (MOFs) constructed from semi-flexible 4-(3,5-dicarboxylatobenzyloxy)benzoic acid (H3L), namely {[Co1.5(HL)(4,4′-bidpe)2(H2O)]·3H2O}n (1), {[Co3(L)2(4,4′-bibp)3(μ2-O)2]·2H2O}n (2), {[Co(HL)(1,3-bitl)]·(1,4-Diox)}n (3), [Co2(HL)2(3,5-bipd)2]n (4), and {[Co(HL)(tib)]·0.5H2O·NMP}n (5) (4,4′-bidpe = 4,4′-bis(imidazolyl)diphenyl ether, 4,4′-bibp = 4,4′-bis(imidazol-1-yl)biphenyl, 1,3-bitl = 1,3-bis(1-imidazoly)toluene, 3,5-bipd… read more here.
Keywords: nodal connected; flexible dicarboxylatobenzyloxy; semi flexible; unprecedented nodal ... See more keywords