Dearomatization and Functionalization of Terpyridine Ligands Leading to Unprecedented Zwitterionic Meisenheimer Aluminum Complexes and Their Use in Catalytic Hydroboration
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DOI: 10.1021/acscatal.8b04096
Abstract: This paper reports the first example of dearomatization of ubiquitous terpyridine (tpy) ligands via 2′/6′-, 3′/5′-, or 4′-selective alkylation of the central pyridine ring. The reaction is mediated by the most abundant metal in the… read more here.
Keywords: terpyridine; unprecedented zwitterionic; zwitterionic meisenheimer; dearomatization ... See more keywords