Efficient Synthesis of Cyclic Carbonates from Unsaturated Acids and Carbon Dioxide and their Application in the Synthesis of Biobased Polyurethanes.
Sign Up to like & getrecommendations! Published in 2021 at "ChemPlusChem"
DOI: 10.1002/cplu.202100079
Abstract: Bio-derived furan- and diacid-derived cyclic carbonates have been synthesized in high yields from terminal epoxides and CO2 . Furthermore, four highly substituted terpene-derived cyclic carbonates were isolated in good yields with excellent diastereoselectivity in some… read more here.
Keywords: synthesis cyclic; efficient synthesis; unsaturated acids; carbonates unsaturated ... See more keywords
Synthesis of α,α-difluorobenzoyl oxygen heterocycles via the radical reaction of 2-iodo-2,2-difluoroacetophenones with unsaturated acids or unsaturated alcohols
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2017.06.003
Abstract: Abstract A convenient and facile method for the direct synthesis of α,α-difluorobenzoyl lactones or cyclic ethers via the radical cyclization reaction of 2-iodo-2,2-difluoroacetophenone with unsaturated acids or alcohols was reported. read more here.
Keywords: unsaturated acids; reaction iodo; synthesis difluorobenzoyl; via radical ... See more keywords
Two symmetrical unsaturated acids isolated from Viscum album.
Sign Up to like & getrecommendations! Published in 2019 at "Chinese journal of natural medicines"
DOI: 10.1016/s1875-5364(19)30016-0
Abstract: In the present study, two new acetylene conjugate compounds, dibutyl (2Z, 6Z)-octa-2, 6-dien-4-yne dioate (1), and dibutyl (2E, 6E)- octa-2, 6-dien-4-yne dioate (2), were isolated from the dry stem leaves of Viscum album, along with… read more here.
Keywords: acids isolated; viscum album; isolated viscum; symmetrical unsaturated ... See more keywords
Visible-Light-Induced Decarboxylative Annulation of α,β-Unsaturated Acids with Amines and α-Keto Acids for 2,4-Diarylquinoline Synthesis.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c00099
Abstract: An efficient and sustainable approach for the synthesis of 2,4-diarylquinolines has been developed via a visible-light-promoted metal-free three-component decarboxylative annulation pathway. This one-pot protocol combines readily available feed-stock α,β-unsaturated acids, aromatic amines, and α-keto acids… read more here.
Keywords: annulation; visible light; unsaturated acids; decarboxylative annulation ... See more keywords
Photoinduced, Copper-Promoted Regio- and Stereoselective Decarboxylative Alkylation of α,β-Unsaturated Acids with Alkyl Iodides.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b03289
Abstract: The first example of UV light-induced, copper-catalyzed regio- and stereoselective decarboxylative coupling of α,β-unsaturated acids with alkyl iodides was reported. Under standard conditions, the 1°, 2°, and 3° alkyl iodides proceeded smoothly with the E-selective… read more here.
Keywords: alkyl iodides; unsaturated acids; acids alkyl; copper ... See more keywords
Decarboxylative chlorination of α,β-unsaturated acids.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc03038b
Abstract: Herein, an unprecedented oxidative decarboxylative chlorination of α,β-unsaturated acids for α-chloroketones is reported. This green and sustainable approach employs Fe(III)-catalyzed LMCT to generate a chloride radical from non-hazardous LiCl under violet light irradiation. Molecular oxygen… read more here.
Keywords: chlorination unsaturated; unsaturated acids; decarboxylative chlorination;