Silver-promoted (radio)fluorination of unsaturated carbamates via a radical process.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01393k
Abstract: The intramolecular fluorocyclization of unsaturated carbamates is described here using a hypervalent iodine reagent in the presence of a silver catalyst. Both (hetero)aryl-substituted olefins and acrylamides can be utilized as effective substrates. Preliminary mechanistic investigations… read more here.
Keywords: promoted radio; radical process; fluorination; unsaturated carbamates ... See more keywords