Computational study on the NHC-catalyzed synthesis of 2,3-disubstituted indoles: mechanism, key intermediate and the role of the catalyst
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DOI: 10.1039/c8qo00139a
Abstract: In this work, the possible reaction mechanisms and the role of N-heterocyclic carbene (NHC) catalysts in the umpolung reaction of imines to generate 2-substituted indole-3-acetic acid derivatives were investigated by density functional theory (DFT). Two… read more here.
Keywords: carbon; unsaturated ester; carbon unsaturated; imine carbon ... See more keywords
Screening for Volatile α-Unsaturated Ester-Producing Yeasts from the Feces of Wild Animals in South Africa
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DOI: 10.3390/life12121999
Abstract: α-unsaturated esters are fruity-aromatic compounds which are largely spread in the volatilome of many different fruits, but they are rarely found in the volatilome of yeasts. The yeast S. suaveolens has been recently shown to… read more here.
Keywords: unsaturated ester; screening volatile; ester producing; unsaturated esters ... See more keywords