Reactive carbon fiber ionization-mass spectrometry for characterization of unsaturated hydrocarbons from plant aroma
Sign Up to like & getrecommendations! Published in 2020 at "Analytical and Bioanalytical Chemistry"
DOI: 10.1007/s00216-020-02769-4
Abstract: Carbon fiber ionization (CFI)-mass spectrometry (MS) is an ambient technique that can be used to detect samples in gas, liquid, and solid forms simply by using a piece of carbon fiber as the ionization emitter.… read more here.
Keywords: unsaturated hydrocarbons; carbon fiber; carbon; mass ... See more keywords
Formation of Unsaturated Hydrocarbons and Hydrogen: Surface Chemistry of Methyltrioxorhenium(VII) in ALD of Mixed-Metal Oxide Structures Comprising Re(III) Units
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.9b01408
Abstract: We present the full investigation of the atomic layer deposition (ALD) of a mixed rhenium–aluminum oxide, namely ReAl2O3CH3, a material with tunable resistance, comprising the building unit of cond... read more here.
Keywords: unsaturated hydrocarbons; hydrogen surface; hydrocarbons hydrogen; chemistry ... See more keywords
CH Bond Activation of Unsaturated Hydrocarbons by a Niobium Methyl Cyclopropyl Precursor. Cyclopropyl Ring Opening and Alkyne Coupling Reaction
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.6b00506
Abstract: The transient intermediate η2-cyclopropene/bicyclobutane niobium complex [TpMe2Nb(η2-c-C3H4)(MeCCMe)] A, generated by an intramolecular β-H abstraction of methane from the methyl cyclopropyl complex [TpMe2NbMe(c-C3H5)(MeCCMe)] (1), is able to cleave the CH bond of a variety of unsaturated… read more here.
Keywords: unsaturated hydrocarbons; meccme; bond; cyclopropyl ... See more keywords
Phosphinothio(seleno)ation of alkynes/olefins and application on the late-stage functionalization of natural products
Sign Up to like & getrecommendations! Published in 2024 at "Communications Chemistry"
DOI: 10.1038/s42004-024-01326-9
Abstract: Non-metallic catalysis has been known as a remarkable development strategy for hydrofunctionalization of unsaturated hydrocarbons. Herein, we report a unique chemically active method of BF3·OEt2 promoted multi-component, highly regioselective, and chemoselective hydrothio(seleo)phosphonylation of unsaturated hydrocarbons,… read more here.
Keywords: non metallic; hydrofunctionalization unsaturated; natural products; unsaturated hydrocarbons ... See more keywords
Optimizing semi-hydrogenation of unsaturated hydrocarbons by electrolyte engineering approach
Sign Up to like & getrecommendations! Published in 2025 at "Chemical Science"
DOI: 10.1039/d5sc03012a
Abstract: Electrochemical hydrogenation of unsaturated hydrocarbons, when powered by renewables, represents a unique opportunity to substitute current energy-intensive synthetic routes. Modulation of adsorption energies of the organic substrate and key intermediates of the reaction is critical… read more here.
Keywords: reaction; spectroscopy; hydrogenation unsaturated; hydrogenation ... See more keywords
Estimate of Hyperconjugation Strength in Alkylaromatics and Unsaturated Hydrocarbons Derived from Refractometric Data
Sign Up to like & getrecommendations! Published in 2020 at "Current Organic Chemistry"
DOI: 10.2174/1385272823666191108100747
Abstract: A retrospective view of exaltation of refraction observed for many unsaturated and aromatic compounds demonstrates that this physical phenomenon is undeservedly considered only as a qualitative measure of conjugation. This mini-review discusses numerous papers by… read more here.
Keywords: unsaturated hydrocarbons; hyperconjugation strength; estimate hyperconjugation; strength alkylaromatics ... See more keywords