Synthesis and characterization of unsaturated Manganese(I) and Rhenium(I) dicarbonyl complexes supported by an anionic PNP pincer
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DOI: 10.1016/j.jorganchem.2019.06.020
Abstract: Abstract Syntheses of Re and Mn carbonyl complexes of the diarylamido/bis(phosphine) PNP pincer ligand are reported. The saturated (PNP)Re(CO)3 and (PNP)Mn(CO)3 react cleanly with HBr in acetic acid to undergo decarbonylation with concomitant addition of… read more here.
Keywords: synthesis characterization; unsaturated manganese; characterization unsaturated; pnp ... See more keywords