Enhanced photoelectrochemical hydrogenation of green-house gas CO2 to high-order solar fuel on coordinatively unsaturated metal-N sites containing carbonized Zn/Co ZIFs
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.06.102
Abstract: Abstract Porous carbon-based catalysts facilitate CO2 photoelectrochemical reduction reaction (CO2PRR) through the high charge transfer ability and CO2 adsorption ability. However, the design of catalysts with high selectivity towards high-order solar fuels (such as ethanol… read more here.
Keywords: order solar; order; unsaturated metal; coordinatively unsaturated ... See more keywords
Effect of Unsaturated Metal Site Modulation in Highly Stable Microporous Materials on CO2 Capture and Fixation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03310
Abstract: We have designed and synthesized two unprecedented microporous three-dimensional metal-organic frameworks, {[Cd6(TPOM)3(L)6]·12DMF·3H2O}n (1) and {[Zn2(TPOM)(L)2]·2DMF·H2O}n (2), based on a flexible quadritopic ligand, tetrakis(4-pyridyloxymethylene)methane (TPOM), and a bent dicarboxylic acid, 4,4'-(dimethylsilanediyl)bis-benzoic acid (H2L). The networks of… read more here.
Keywords: topology; modulation; unsaturated metal; metal site ... See more keywords
Layered FeCoNi double hydroxides with tailored surface electronic configurations induced by oxygen and unsaturated metal vacancies for boosting the overall water splitting process.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d2nr00143h
Abstract: Two-dimensional (2D) layered double hydroxides (LDH) with excellent hydrophilic ability and rapid hydroxyl insertion are regarded as one of the most promising electrocatalysts for both the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER)… read more here.
Keywords: oxygen; surface; unsaturated metal; water splitting ... See more keywords