Articles with "unsaturated sites" as a keyword



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In-situ decoration of unsaturated Cu sites on Cu2O photocathode for boosting nitrogen reduction reaction

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Published in 2021 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2020.127453

Abstract: Abstract Photoelectrochemical N2 reduction reaction (PEC NRR) into chemical energy source is a promising technique for solving environmental challenges and the energy crisis, which depends on the exploration of p-type photocathodes. Cu2O is a p-type… read more here.

Keywords: unsaturated sites; reduction reaction; pec nrr;

Direct Observation of Coordinatively Unsaturated Sites on the Surface of a Fluoride-Doped Alumina Catalyst

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Published in 2017 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.7b02535

Abstract: Coordinatively unsaturated sites (CUS) present a key feature of alumina based catalysts as they are believed to act as Lewis-acid sites in heterogeneously catalyzed reactions. In the present study, the direct observation of active species… read more here.

Keywords: fluoride doped; unsaturated sites; direct observation; coordinatively unsaturated ... See more keywords
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Improved Performance of g-C3N4 for Optoelectronic Detection of NO2 Gas by Coupling Metal-Organic Framework Nanosheets with Coordinatively Unsaturated Ni(II) Sites.

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Published in 2023 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.3c00903

Abstract: Sensitive and selective optoelectronic detection of NO2 with g-C3N4 (CN) is critical, but it remains challenging to achieve ultralow concentration (ppb-level) detection. Herein, Ni metal-organic frameworks/CN nanosheet heterojunctions were successfully fabricated by the electrostatic induced… read more here.

Keywords: unsaturated sites; coordinatively unsaturated; detection no2; metal organic ... See more keywords
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Efficient catalysts of surface hydrophobic Cu-BTC with coordinatively unsaturated Cu(I) sites for the direct oxidation of methane.

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Published in 2023 at "Proceedings of the National Academy of Sciences of the United States of America"

DOI: 10.1073/pnas.2206619120

Abstract: Selective oxidation of methane to organic oxygenates over metal-organic frameworks (MOFs) catalysts at low temperature is a challenging topic in the field of C1 chemistry because of the inferior stability of MOFs. Modifying the surface… read more here.

Keywords: unsaturated sites; coordinatively unsaturated; oxidation methane; btc ... See more keywords