Catalytic Activation of Unstrained C(Aryl)-C(Alkyl) Bonds in 2,2'-Methylenediphenols.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13342
Abstract: Catalytic activation of unstrained and nonpolar C-C bonds remains a largely unmet challenge. Here, we describe our detailed efforts in developing a rhodium-catalyzed hydrogenolysis of unstrained C(aryl)-C(alkyl) bonds in 2,2'-methylenediphenols aided by removable directing groups.… read more here.
Keywords: unstrained aryl; activation unstrained; bonds methylenediphenols; aryl alkyl ... See more keywords
Ruthenium-Catalyzed Reductive Cleavage of Unstrained Aryl─Aryl Bonds: Reaction Development and Mechanistic Study.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b11605
Abstract: Cleavage of carbon-carbon bonds has been found in some important industrial processes, e.g. petroleum cracking, and has inspired development of numerous synthetic methods. However, non-polar unstrained C(aryl)-C(aryl) bonds remain one of the toughest bonds to… read more here.
Keywords: unstrained aryl; aryl aryl; cleavage; aryl bonds ... See more keywords