Deconstructive Pyridylation of Unstrained Cyclic Amines through a One-Pot Umpolung Approach.
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DOI: 10.1021/acs.orglett.3c00922
Abstract: A one-pot umpolung method for the ring-opening pyridylation of unstrained cyclic amines was developed using N-amidopyridinium salts. This process involves the formation of electron donor-acceptor complexes between bromide and N-amidopyridinium salts, ultimately leading to the… read more here.
Keywords: pot umpolung; pyridylation unstrained; one pot; unstrained cyclic ... See more keywords