N-Heterocyclic carbene-based ruthenium-hydride catalysts for the synthesis of unsymmetrically functionalized double-decker silsesquioxanes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc01316k
Abstract: Ruthenium-N-heterocyclic carbene complexes with the generic formula [RuHCl(CO)(NHC)(PCy3)] exhibit a high catalytic activity toward the (E)-selective silylative coupling of divinyl-substituted double-decker silsesquioxanes with two distinctly substituted styrenes. This process leads to a novel class of… read more here.
Keywords: ruthenium; decker silsesquioxanes; heterocyclic carbene; double decker ... See more keywords
Unsymmetrically functionalized 5,5″-diaryl- and 5,6,5″-triaryl-2,2′:6′,2″-terpyridines: an efficient synthetic route and photophysical properties
Sign Up to like & getrecommendations! Published in 2017 at "Canadian Journal of Chemistry"
DOI: 10.1139/cjc-2017-0195
Abstract: An efficient approach for the synthesis of 5,5″- or 5,6,5″-aryl substituted 2,2′:6′,2″-terpyridines, bearing an anneleted cyclopentene unit in one of the side-chain pyridine rings for the improved solubility in organic solvents, via their 1,2,4-triazine analogues… read more here.
Keywords: functionalized diaryl; diaryl triaryl; terpyridines efficient; efficient synthetic ... See more keywords