Efficient synthesis of 5-oxatruxene and the unusual influence of oxygen heteroatom on its physico-chemical properties
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DOI: 10.1039/c7nj04729k
Abstract: In this paper, we describe the effective synthesis of oxatruxene and its photophysical, electrochemical and structural features that transpire when a methylene unit in a truxene core is replaced by an oxygen atom to yield… read more here.
Keywords: oxygen; synthesis oxatruxene; oxatruxene unusual; efficient synthesis ... See more keywords
The unusual influence of hetaryl groups on the direct conversion of some secondary alcohols into thiols with Lawesson’s reagent: elucidation of the reaction mechanism
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DOI: 10.1080/17415993.2017.1313257
Abstract: ABSTRACT A series of hetaryl-substituted methanols were used for direct conversion into the corresponding thiols by treatment with Lawesson’s reagent in boiling toluene. Unexpectedly, the respective sulfides were formed exclusively. In the case of chiral… read more here.
Keywords: lawesson reagent; direct conversion; influence hetaryl; unusual influence ... See more keywords