Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential UVI chelation.
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DOI: 10.1039/c9dt04126e
Abstract: Diphenic acid (H2dip) has been used to synthesize nine homo- or heterometallic uranyl ion complexes under solvo-hydrothermal conditions. The diphenate ligand dip2- adopts different coordination modes, mixtures of κ2-O,O'-chelation by individual carboxylate groups, chelation involving… read more here.
Keywords: chelation; coordination; uo2 dip; dip ... See more keywords