Woven, Polycatenated, or Cage Structures: Effect of Modulation of Ligand Curvature in Heteroleptic Uranyl Ion Complexes.
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DOI: 10.1021/acs.inorgchem.3c00432
Abstract: Combining the flexible zwitterionic dicarboxylate 4,4'-bis(2-carboxylatoethyl)-4,4'-bipyridinium (L) and the anionic dicarboxylate ligands isophthalate (ipht2-) and 1,2-, 1,3-, or 1,4-phenylenediacetate (1,2-, 1,3-, and 1,4-pda2-), of varying shape and curvature, has allowed isolation of five uranyl ion… read more here.
Keywords: uranyl ion; uo2 pda; ion complexes; curvature ... See more keywords