Homoleptic Uranium-Bis(acyl)phosphide Complexes.
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DOI: 10.1021/acs.inorgchem.2c00639
Abstract: The first uranium bis(acyl)phosphide (BAP) complexes were synthesized from the reaction between sodium bis(mesitoyl)phosphide (Na(mesBAP)) or sodium bis(2,4,6-triisopropylbenzoyl)phosphide (Na(trippBAP)) and UI3(1,4-dioxane)1.5. Thermally stable, homoleptic BAP complexes were characterized by single-crystal X-ray diffraction and electron paramagnetic… read more here.
Keywords: bis acyl; bis; acyl phosphide; spectroscopy ... See more keywords