Oxidation of uranium(iv) thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains.
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DOI: 10.1039/c9dt01005j
Abstract: Oxidation of Cs4[U(NCS)8] in MeCN or DMF affords structurally characterised examples of the mixed-valent UIV/VI compound Cs14[{U(NCS)8}3{UO2(NCS)4(H2O)}]·4.5H2O, or the [UIV-UV-UIV][UVI] species [U(DMF)8(μ-O)U(NCS)5(μ-O)U(DMF)7(NCS)][UO2(NCS)5]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated… read more here.
Keywords: cation; thiocyanate complexes; uranium thiocyanate; oxidation uranium ... See more keywords