Design of Promising Uranyl(VI) Complexes Thin Films with Potential Applications in Molecular Electronics
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DOI: 10.1002/open.202300219
Abstract: Abstract In this work, it is proposed the development of organic semiconductors (OS) based on uranyl(VI) complexes. The above by means of the synthesis and the characterization of the complexes by Infrared spectroscopy, Nuclear magnetic… read more here.
Keywords: spectroscopy; uranyl complex; uranyl complexes; pyridine position ... See more keywords
Synthesis, Spectroscopic Studies and Supramolecular Architecture in a Dinuclear Uranyl Complex, 2-Aminopyridinium [bis(µ2-hydroxo)-tetrakis(nitrato–κ2–O,O′)-tetraoxo-diuranium(VI)] Monohydrate
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Chemical Crystallography"
DOI: 10.1007/s10870-019-00777-6
Abstract: AbstractThe titled dinuclear uranyl complex, U2O18N4H2·2(C5H7N2) 2(H2O) was crystallised in Monoclinic (C2/c) space group with the cell parameters a = 18.0728(3) b = 10.6896(3) c = 13.9068(3)Å, α = γ = 90.00° β = 103.988(2)°. In the structure, the U(VI) atom is eight coordinated with slightly distorted… read more here.
Keywords: atom; spectroscopic studies; dinuclear uranyl; synthesis spectroscopic ... See more keywords
Synthesis and characterization of a uranyl(VI) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative.
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DOI: 10.1039/d2dt00325b
Abstract: A uranyl(VI) complex with 2,6-bis(3,5-di-tert-butyl-o-phenolateaminomethyl)pyridine (UO2(tBu-pdaop), 1) was synthesized and thoroughly characterized by 1H NMR, IR, elemental analysis, and single-crystal XRD. Right after the dissolution of complex 1 in pyridine or DMSO, the solution was… read more here.
Keywords: aerobic oxidation; bis; complex pyridine; pyridine ... See more keywords
Synthesis and characterization of an amethyrin-uranyl complex displaying aromatic character
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DOI: 10.1080/00958972.2018.1458230
Abstract: Abstract The reaction between amethyrin and non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2) under anaerobic conditions affords a bench-stable uranyl complex. UV–vis spectroscopy, cyclic voltammetry, as well as proton NMR spectroscopic analyses provide support for the conclusion that… read more here.
Keywords: characterization amethyrin; uranyl complex; displaying aromatic; amethyrin uranyl ... See more keywords