Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo- and Heterometallic Species, Including a Novel Uranyl-Lanthanide Complex
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700283
Abstract: Reaction of uranyl nitrate with cucurbit[6]uril (CB6) and carboxylic or sulfonic acid ligands under hydrothermal conditions and in the presence of additional metal cations (KI or CeIII) or co-solvents provided four complexes which were crystallographically… read more here.
Keywords: complexes scaffolding; uranyl complexes; scaffolding spacers; cb6 ... See more keywords
Design of Promising Uranyl(VI) Complexes Thin Films with Potential Applications in Molecular Electronics
Sign Up to like & getrecommendations! Published in 2024 at "ChemistryOpen"
DOI: 10.1002/open.202300219
Abstract: Abstract In this work, it is proposed the development of organic semiconductors (OS) based on uranyl(VI) complexes. The above by means of the synthesis and the characterization of the complexes by Infrared spectroscopy, Nuclear magnetic… read more here.
Keywords: spectroscopy; uranyl complex; uranyl complexes; pyridine position ... See more keywords
Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2017.10.012
Abstract: Abstract In this paper, two new uranyl complexes (H2-bpp)[(UO2)(p-nba)3]2 1 and (H2-bipy)[(UO2)4(μ3–O)2(p-nba)6] 2 were synthesized by hydrothermal method base on the reaction of UO2Ac2·2H2O as the metal sources, p-nitrobenzoic acid (Hp-nba), 4,4′-bipyridine (bipy) and 1,3-di(4-pyridyl)-propane… read more here.
Keywords: uranyl complexes; two new; degradation tetracycline; visible light ... See more keywords
Main-Group Metals Stabilized Polypyrrolic Uranyl(V) Complexes via Cation-Cation Interaction with the Uranyl exo-Oxo Atom: A Relativistic Density Functional Theory Study.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02406
Abstract: To explore the innovative uranyl(V) complexes by deeply understanding their coordination stability, relativistic density functional theory calculations have been performed to investigate the experimentally reported [(py)(R2AlOUVO)(py)(H2L)] [R = Me (1), iBu (2)] and [{(py)3MOUVO}(py)(H2L)] [M… read more here.
Keywords: cation; theory; uranyl complexes; uranyl exo ... See more keywords
Core-Excited States of Linear and Bent Uranyl Complexes: Insights from High-Energy Resolution X-ray Spectroscopy and Relativistic Quantum Chemistry.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04245
Abstract: Advanced X-ray spectroscopic techniques are widely recognized as state-of-the-art tools for probing the electronic structure, bonding, and chemical environments of the heaviest elements in the periodic table. In this study, we employ X-ray absorption near-edge… read more here.
Keywords: spectroscopy; high energy; chemistry; relativistic quantum ... See more keywords
Breaking C–O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b01408
Abstract: We report herein the possibility to perform the hydrosilylation of carbonyls using actinide complexes as catalysts. While complexes of the uranyl ion [UO2]2+ have been poorly considered in catalysis, we show the potentialities of the… read more here.
Keywords: breaking bonds; hydrosilylation; uranyl complexes; bonds uranium ... See more keywords
Enhanced luminescence of tris(carboxylato)uranyl(VI) complexes and energy transfer to Eu(III): a combined spectroscopic and theoretical investigation.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00849a
Abstract: Complex formation between uranyl and carboxylate ligands (benzoate, nicotinate and isonicotinate) has been studied extensively by absorption and luminescence spectroscopy in acetonitrile medium. Experimental data had indicated the existence of stable and enhanced luminescent tris(carboxylato)… read more here.
Keywords: transfer; uranyl complexes; tris carboxylato; iii ... See more keywords