Structural Diversity of Bipyridinium-Based Uranyl Coordination Polymers: Synthesis, Characterization, and Ion-Exchange Application.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02106
Abstract: As well-known functional groups with excellent electro/photochromic and ion-exchange properties, bipyridinium motifs have been used in functionalized metal-organic coordination polymers, but they are still rarely applied to construct actinide coordination polymers. In this work, we… read more here.
Keywords: uranyl coordination; coordination; ion exchange; chemistry ... See more keywords
Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Materials Chemistry C"
DOI: 10.1039/d0tc02623a
Abstract: A new uranyl-coordination polymer (UCP) has been solvothermally synthesized employing succinic acid and 1,10-phenanthroline (phen) as ligands. The obtained compound with the formula [(UO2)2(phen)(succ)0.5(OH)(O)4(μ3-O)(H2O)]·H2O (UNSL-1) is classified as 1D chains showing I0O1 connectivity. Also, the… read more here.
Keywords: like uranyl; uranyl coordination; chain like; coordination polymer ... See more keywords
Enhancing photosensitivity via the assembly of a uranyl coordination polymer.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02985e
Abstract: Synergistic assembly of uranyl centres and luminescent 2,6-bis(pyrazol-1-yl)pyridine-4-carboxylates (bppCOOH) gives rise to a uranyl coordination polymer, namely U-bppCOO, which exhibits a luminescence quenching response toward UV or X-ray irradiation doses. Notably, the photosensitivity of U-bppCOO… read more here.
Keywords: uranyl coordination; assembly uranyl; coordination polymer;