Remote Asymmetric Induction Using Acetate-Type Vinylketene Silyl N,O-Acetals.
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DOI: 10.1021/acs.orglett.6b03476
Abstract: Remote asymmetric induction by the vinylogous Mukaiyama aldol reaction using the acetate-type vinylketene silyl N,O-acetal possessing a chiral auxiliary has been achieved. The silyl N,O-acetal derived from crotonate and l-valine afforded the O-silylated 5R- and… read more here.
Keywords: using acetate; acetate type; asymmetric induction; vinylketene silyl ... See more keywords