Palladium-Catalyzed Siloxycyclopropanation of Alkenes Using Acylsilanes.
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DOI: 10.1021/jacs.1c11497
Abstract: Currently, catalytically transferable carbenes are limited to electron-deficient and neutral derivatives, and electron-rich carbenes bearing an alkoxy group (i.e., Fischer-type carbenes) cannot be used in catalytic cyclopropanation because of the lack of appropriate carbene precursors.… read more here.
Keywords: catalyzed siloxycyclopropanation; using acylsilanes; alkenes using; siloxycyclopropanation alkenes ... See more keywords