Enantioselective Radical Reactions Using Chiral Catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.1c00582
Abstract: Benefiting from the impressive increase in fundamental knowledge, the last 20 years have shown a continuous burst of new ideas and consequently a plethora of new catalytic methods for enantioselective radical reactions. This review aims… read more here.
Keywords: chiral catalysts; review; using chiral; radical reactions ... See more keywords
Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c05245
Abstract: A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance of alkoxide bulkiness and complex chirality in inducin... read more here.
Keywords: chirality induced; catalyst aggregation; aluminum; induced catalyst ... See more keywords
Circularly polarized light detection using chiral hybrid perovskite
Sign Up to like & getrecommendations! Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-019-09942-z
Abstract: Circularly polarized light (CPL) detection is required in various fields such as drug screening, security surveillance and quantum optics. Conventionally, CPL photodetector needs the installation of optical elements, imposing difficulties for integrated and flexible devices.… read more here.
Keywords: polarized light; circularly polarized; hybrid perovskite; light detection ... See more keywords
Direct catalytic enantioselective Mannich-type reaction of α,α-dithioacetonitriles with imines using chiral bis(imidazoline)-Pd complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc03307a
Abstract: The first highly enantioselective reaction of α,α-dithioacetonitriles with imines has been developed. Good yields and enantioselectivity were observed for the reaction of various imines using chiral bis(imidazoline) catalysts. The obtained products can be converted into… read more here.
Keywords: reaction dithioacetonitriles; chiral bis; reaction; imines using ... See more keywords
Catalytic and enantioselective oxa-Piancatelli reaction using a chiral vanadium complex.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc02621b
Abstract: An enantioselective oxa-Piancatelli reaction was established for the first time using a chiral vanadium(v) catalyst. The dual Brønsted and Lewis acid properties of the vanadium catalyst afforded 4-hydroxycyclopent-2-enone derivatives in up to 90% yields and… read more here.
Keywords: piancatelli reaction; oxa piancatelli; chiral vanadium; enantioselective oxa ... See more keywords
Potential for Underestimation of d-Methylphenidate Bioavailability Using Chiral Derivatization/Gas Chromatography
Sign Up to like & getrecommendations! Published in 2019 at "Drug Metabolism and Disposition"
DOI: 10.1124/dmd.119.087189
Abstract: A tenable hypothesis is presented which explains disparities between older oral dl-MPH bioavailability data generated using chiral derivatization-gas chromatography versus more recent findings using chiral liquid chromatography. These disparities persist in current literature. The gas… read more here.
Keywords: mph; bioavailability; gas; chiral derivatization ... See more keywords
Microfluidic sensor applications by using chiral metamaterial
Sign Up to like & getrecommendations! Published in 2020 at "Modern Physics Letters B"
DOI: 10.1142/s0217984920500311
Abstract: Chiral metamaterial-based sensor is designed for sensing the change in substance ratio of chemical substances when combined with distilled water. These samples have been prepared with 10%, 50% and ... read more here.
Keywords: sensor applications; chiral metamaterial; applications using; microfluidic sensor ... See more keywords