Photoredox Catalyzed Thioformylation of Terminal Alkynes Using Nitromethane as a Formyl Source.
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DOI: 10.1021/acs.orglett.2c02695
Abstract: A photoredox thioformylation of terminal alkynes using nitromethane as a formyl anion equivalent, thereby leading to the synthesis of (E)-1,2-difunctionalized acrylaldehyde, has been described. The current strategy introduces an adaptable aldehyde function across an alkyne… read more here.
Keywords: thioformylation terminal; nitromethane formyl; using nitromethane; terminal alkynes ... See more keywords
Copper-catalyzed Cyanation of Aryl Iodides Using Nitromethane
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DOI: 10.1246/cl.170798
Abstract: The copper-catalyzed cyanation of aryl iodides is described using nitromethane as a CN source. In situ generation of a “CN” species from nitromethane is plausible. This strategy is an advantageous synthetic method for the construction… read more here.
Keywords: aryl iodides; cyanation aryl; using nitromethane; cyanation ... See more keywords