Ligand-based reduction of nitrate to nitric oxide utilizing a proton-responsive secondary coordination sphere.
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DOI: 10.1039/c7cc06541h
Abstract: Utilizing the proton-responsive pyridinediimine ligand [(2,6-iPrC6H3)(N[double bond, length as m-dash]CMe)(N(iPr)2C2H4)(N[double bond, length as m-dash]CMe)C5H3N] (didpa), the ligand-based reduction of nitrate (NO3-) to nitric oxide (NO) was achieved. The bioinspired [Fe(Hdidpa)(CO)2]+ was shown to react with… read more here.
Keywords: reduction; ligand based; reduction nitrate; utilizing proton ... See more keywords