Interface Switchable Bonding Tailored Ruthenium Sites Unveil Ultralow Overpotentials for Hydrogen Evolution
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202414758
Abstract: Controlling the electronic structure based on the valence state is key for effective electrocatalysis, and the challenge lies in attaining the optimal metal valence states. Here, a new approach called valence‐elastic control is introduced to… read more here.
Keywords: valence; switchable bonding; hydrogen evolution; bonding tailored ... See more keywords
Tuning Mixed‐Valence State in Coordination Polymers for Electronics and Optics
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202516680
Abstract: Coordination‐assembled systems have attracted much attention in physics and chemistry because of their structural tunability and wide variety of building units; however, their functionalities are often limited because of the difficulty in controlling dynamic or… read more here.
Keywords: valence; optics; coordination polymers; mixed valence ... See more keywords
Mixed-Valence Single-Atom Catalyst Derived from Functionalized Graphene.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201900323
Abstract: Single-atom catalysts (SACs) aim at bridging the gap between homogeneous and heterogeneous catalysis. The challenge is the development of materials with ligands enabling coordination of metal atoms in different valence states, and preventing leaching or… read more here.
Keywords: graphene; valence single; valence; mixed valence ... See more keywords
Motivational and Valence‐Related Modulation of Sleep/Wake Behavior are Mediated by Midbrain Dopamine and Uncoupled from the Homeostatic and Circadian Processes
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202200640
Abstract: Motivation and its hedonic valence are powerful modulators of sleep/wake behavior, yet its underlying mechanism is still poorly understood. Given the well‐established role of midbrain dopamine (mDA) neurons in encoding motivation and emotional valence, here,… read more here.
Keywords: sleep wake; modulation; modulation sleep; motivational valence ... See more keywords
Multiple Valence Bands Convergence and Localized Lattice Engineering Lead to Superhigh Thermoelectric Figure of Merit in MnTe.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced science"
DOI: 10.1002/advs.202206342
Abstract: MnTe has been considered a promising candidate for lead-free mid-temperature range thermoelectric clean energy conversions. However, the widespread use of this technology is constrained by the relatively low-cost performance of materials. Developing environmentally friendly thermoelectrics… read more here.
Keywords: localized lattice; mnte; lattice engineering; convergence localized ... See more keywords
Direct evaluative conditioning in brand placement: The impact of scene valence and prominence on brand placement repetition effects
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Consumer Behaviour"
DOI: 10.1002/cb.1647
Abstract: Whereas previous studies investigated the affect transfer from one specific affective stimulus of the brand placement context (such as an artist or the genre) to the brand, this research study investigates the effect of the… read more here.
Keywords: brand; valence; placement; prominence ... See more keywords
Latent structure of negative valence measures in childhood
Sign Up to like & getrecommendations! Published in 2017 at "Depression and Anxiety"
DOI: 10.1002/da.22656
Abstract: Internalizing disorders (IDs), consisting of the syndromes of anxiety and depression, are common, debilitating conditions often having onsets in adolescence. Scientists have developed dimensional self‐report instruments that assess putative negative valence system (NVS) trait‐like constructs… read more here.
Keywords: valence measures; valence; negative valence; latent structure ... See more keywords
Validating the theoretical bases of sleep reactivation during sharp‐wave ripples and their association with emotional valence
Sign Up to like & getrecommendations! Published in 2019 at "Hippocampus"
DOI: 10.1002/hipo.23143
Abstract: Sleep is important for memory consolidation, and an abundant literature suggests that reactivation in the hippocampus during sleep is instrumental to this process. Yet, the current interpretation of activity during sharp‐waves ripples (SWRs), as replay… read more here.
Keywords: theoretical bases; reactivation; valence; emotional valence ... See more keywords
CSiGaAl2−/0 and CGeGaAl2−/0 having planar tetracoordinate carbon atoms in their global minimum energy structures
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26845
Abstract: Density functional theory (DFT) is used to explore the structure, stability, and bonding in CSiGaAl2−/0 and CGeGaAl2−/0 systems having planar tetracoordinate carbon (ptC). The neutral systems have 17 valence electrons and the mono‐anionic systems have… read more here.
Keywords: valence; tetracoordinate carbon; csigaal2 cgegaal2; planar tetracoordinate ... See more keywords
Operando High-Valence Cr-Modified NiFe Hydroxides for Water Oxidation.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202200303
Abstract: High-valence metal-doped multimetal (oxy)hydroxides outperform noble metal electrocatalysts for the oxygen evolution reaction (OER) owing to the modified energetics between 3d metals and high-valence dopants. However, the rational design of sufficient and subtle modulators is… read more here.
Keywords: nifecr ldh; water; operando high; high valence ... See more keywords
Dynamic Induction of Conversion-Based Anode Degradation by Valence State and Mechanical Cracks.
Sign Up to like & getrecommendations! Published in 2025 at "Small"
DOI: 10.1002/smll.202502795
Abstract: Electrochemical energy storage through conversion reactions in crystalline electrode materials primarily depends on the size of guest ions. In this study, a combination of synchrotron-based transmission X-ray microscopy and X-ray absorption near edge spectroscopy is… read more here.
Keywords: induction conversion; valence; conversion; conversion based ... See more keywords