Investigation of the electron transfer properties between metal centers in binuclear and trinuclear cyanido-bridged mixed valence complexes with cis/trans-configuration.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01313d
Abstract: To investigate the electron transfer properties between metal centers and their influencing factors in binuclear and trinuclear cyanido-bridged mixed valence complexes with cis/trans-configuration, binuclear cis-[Cp(dppe)Fe(μ-NC)Ru(5,5'-dmbpy)2(μ-CN)][PF6]n (cis-1[PF6]n, n = 1, 2) and trinuclear cis/trans-[Cp(dppe)Fe(μ-NC)Ru(5,5'-dmbpy)2(μ-CN)Fe(dppe)Cp][PF6]n (cis/trans-2[PF6]n, n… read more here.
Keywords: valence complexes; cyanido bridged; cis; mixed valence ... See more keywords
Synthesis and Characterization of a New Series of Binuclear Pd(II) Biscatecholato Complexes: Non-Innocent Ligand-Based Approach to a Wide Range of Variation in Near-Infrared Absorptions of Mixed-Valence Complexes
Sign Up to like & getrecommendations! Published in 2018 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20180187
Abstract: In this study, we report synthesis of a new series of mixed-valence (MV) complexes having intervalence charge transfer (IVCT) energies variable from the first to the third telecommunication window.... read more here.
Keywords: valence complexes; new series; mixed valence; synthesis characterization ... See more keywords