Characterization of a Mixed-Valence Ru(II)/Ru(III) Ion-Pair Complex. Unexpected High-Frequency Electron Paramagnetic Resonance Evidence for Ru(III)-Ru(III) Dimer Coupling.
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DOI: 10.1021/acs.inorgchem.0c01068
Abstract: In this contribution, we report the synthesis and full characterization of the first mixed-valence Ru(II)/Ru(III) ion-pair complex, [RuII(bipy)2(pic)]+[cis-RuIIICl2(pic)2]-, in the solid state and in aqueous solution, where bipy = 2,2'-bipyridine and pic- = picolinate. In… read more here.
Keywords: valence iii; pair complex; iii ion; mixed valence ... See more keywords
Synthesis of Nanostructured Mixed-Valence Fe(II,III) Metal-Organic Framework and Its Application in Electrochemical Sensing of Amoxicillin
Sign Up to like & getrecommendations! Published in 2023 at "Journal of The Electrochemical Society"
DOI: 10.1149/1945-7111/acced6
Abstract: The study reports the development of a nanostructured mixed-valence Fe(II)Fe(III)BTC metal-organic framework (BTC = 1,3,5-benzenetricarboxylate) modified carbon paste electrode as a novel sensor for the amoxicillin detection in aqueous solutions using square wave voltammetry. The… read more here.
Keywords: spectroscopy; nanostructured mixed; microscopy; valence iii ... See more keywords