Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism.
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DOI: 10.1021/acs.inorgchem.2c02659
Abstract: Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing a range of molecular materials for sensing, memory, and optoelectronic applications. However, these phenomena arise only when specific metal-ligand combinations are employed. The… read more here.
Keywords: state; cobalt; valence tautomerism; valence ... See more keywords
Synergistic valence tautomerism and fluorescence emission in a two-dimensional coordination polymer.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05883a
Abstract: A tetradentate ligand, 1,1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (TPPE), was adopted to construct a two-dimensional coordination polymer that incorporated valence tautomerism and luminescence, and the synergistic effect arising from energy transfer from TPPE to the semiquinone moieties was experimentally… read more here.
Keywords: dimensional coordination; valence tautomerism; two dimensional; coordination polymer ... See more keywords