Low-Valent Manganese Atoms Stabilized on Ceria for Nitrous Oxide Synthesis.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202211260
Abstract: N2 O exhibits unique reactivity in oxidation catalysis, but the high manufacturing costs limit its prospective uses. Direct oxidation of NH3 to N2 O can ameliorate this issue but its implementation is thwarted by suboptimal… read more here.
Keywords: low valent; valent manganese; stabilized ceria; manganese atoms ... See more keywords
Aliphatic and Aromatic C-H Bond Oxidation by High-Valent Manganese(IV)-Hydroxo Species.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08531
Abstract: The strong C-H bond activation of hydrocarbons is a difficult reaction in environmental and biological chemistry. Herein, a high-valent manganese(IV)-hydroxo complex, [MnIV(CHDAP-O)(OH)]2+ (2), was synthesized and characterized by various physicochemical measurements, such as ultraviolet-visible (UV-vis),… read more here.
Keywords: oxidation; valent manganese; manganese hydroxo; electron transfer ... See more keywords