Visible light generation of high-valent metal-oxo intermediates and mechanistic insights into catalytic oxidations.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111246
Abstract: High-valent metal-oxo complexes play central roles as active oxygen atom transfer (OAT) agents in many enzymatic and synthetic oxidation catalysis. This review focuses on our recent advances in application of photochemical approaches to probe the… read more here.
Keywords: oxo species; oxo; valent metal; high valent ... See more keywords
Lone-Pair-Induced Structural Ordering in the Mixed-Valent 0D Metal-Halides Rb23BiIIIxSbIII7–xSbV2Cl54 (0 ≤ x ≤ 7)
Sign Up to like & getrecommendations! Published in 2021 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.0c04491
Abstract: Mixed-valent metal-halides containing ns2 lone pairs may exhibit intense visible absorption, while zero-dimensional (0D) ns2-based metal-chlorides are generally colorless but have demonstrated promising optoelectronic properties suitable for thermometry and radiation detection. Here, we report solvothermally… read more here.
Keywords: rb23biiiixsbiii7 xsbv2cl54; metal; valent metal; metal halides ... See more keywords
Direct, One-Pot Syntheses of MOFs Decorated with Low-Valent Metal-Phosphine Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00319
Abstract: We demonstrate a simple and generalizable method for the one pot, in situ formation of bimetallic metal–organic framework (MOF) materials decorated with crystallographically defined, low-valent metal sites. Solvothermal reactions between poly(carboxylated) aryl(phosphine) ligands and mixtures… read more here.
Keywords: metal; low valent; valent metal; one pot ... See more keywords