Enantioselective Double Carbonylation Enabled by High-Valent Palladium Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10559
Abstract: Palladium-catalyzed carbonylation reactions are efficient methods for synthesizing valuable molecules. However, realizing a carbonylation with excellent yield and chemo-, regio-, and enantioselectivities by classical low-valent palladium catalysis is highly challenging. Herein, we describe an enantioselective… read more here.
Keywords: palladium catalysis; valent palladium; carbonylation; palladium ... See more keywords
Mixed-valent palladium(IV/II)-oxoanion, [PdIVO6PdII6((CH3)2AsO2)6]2.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc05699b
Abstract: We report on the first example of a PdIV-containing polyoxopalladate(II). The discrete mixed-valent polyoxopalladate(IV/II), [PdIVPdII6O6((CH3)2AsO2)6]2-, comprising a central PdIV ion that is surrounded by a six-membered PdII-oxo ring capped by six dimethylarsinate groups, was synthesized… read more here.
Keywords: palladium oxoanion; valent palladium; oxoanion pdivo6pdii6; mixed valent ... See more keywords