Moderate supercritical synthesis as a facile route to mixed-valent uranium(iv,v) and (v,vi) silicates.
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DOI: 10.1039/c8cc07789d
Abstract: Mixed-valent uranium(iv,v) and (v,vi) phases represent a unique subset of known uranium compounds. Efforts to develop our current understanding of these materials have pointed to hydrothermal methods as effective preparative techniques. Herein we report the… read more here.
Keywords: supercritical synthesis; valent uranium; moderate supercritical; mixed valent ... See more keywords
Synthesis and characterization of a low-valent uranium complex supported by a redox-active molybdenum oxide metalloligand.
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DOI: 10.1039/d5cc05531h
Abstract: Investigation of the reactivity of the redox-active molybdenum oxide cluster, , toward low-valent uranium (, bpy = 2,2'-bipyridine) is reported. Structural and spectroscopic analyses provide insight into the interactions of the actinide and metalloligand in… read more here.
Keywords: active molybdenum; valent uranium; redox active; molybdenum oxide ... See more keywords