The Simpler the Better: One‐pot Production of γ‐Valerolactone from Biomass Conversion through All‐In‐One Sc(OTf)3 Catalyzed Cascade Reaction
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202300637
Abstract: γ‐Valerolactone (GVL) derived from non‐edible biomass resources has attracted much intense attention from both academia and industry, due to its excellent properties as green solvent and ideal renewable feedstock for production of bioenergy and biorefinery.… read more here.
Keywords: conversion one; pot; one otf; one pot ... See more keywords
Falling Leaves Return to Their Roots: A review on the Preparation of γ-Valerolactone from Lignocellulose and Its Application in the Conversion of Lignocellulose.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202002008
Abstract: γ-valerolactone (GVL), derived from renewable lignocellulosic biomass, has been considered as a cost-competitive and green platform chemical. With the increasingly prominent environmental problems, the deep study of GVL is highly needed. Based on the latest… read more here.
Keywords: roots review; gvl; falling leaves; application ... See more keywords
One-Pot Conversion of Biomass Saccharides to γ-Valerolactone over a Versatile Tin-Containing Material.
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DOI: 10.1002/cssc.202401416
Abstract: The synthesis of biofuel γ-valerolactone (GVL) from accessible biomass is an attractive and challenging goal. Here, we report an efficient, one-pot, and mild strategy for the efficient production of GVL from various biomass saccharides without… read more here.
Keywords: biomass saccharides; containing material; one pot; tin containing ... See more keywords
Steering Acid-base Site Distribution and Hydrophobicity of Bioresourced Bifunctional Hybrid Materials for Direct Synthesis of γ-Valerolactone from Biomass-based Furfural.
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DOI: 10.1002/cssc.202402165
Abstract: The direct production of value-added chemicals from biomass via multiple conversion processes with a sole renewable solid catalyst is promising for carbon-neutral development while challenging. Herein, a series of novel bioresourced organic-inorganic hybrid materials were… read more here.
Keywords: valerolactone; biomass; hybrid materials; acid base ... See more keywords
Solubility behavior of γ-valerolactone + n-tetradecane or diesel mixtures at different temperatures
Sign Up to like & getrecommendations! Published in 2019 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2018.11.012
Abstract: Abstract Bio-based products and processes were favored recently, because shifting towards a more sustainable economy might be a long-term solution for global challenges. Within this context, γ-valerolactone emerges as a sustainable alternative for industrially relevant… read more here.
Keywords: valerolactone; diesel; solubility; solubility behavior ... See more keywords
Determination of γ-valerolactone content in its synthesis and biorefinery processes by headspace analysis technique
Sign Up to like & getrecommendations! Published in 2018 at "Fuel"
DOI: 10.1016/j.fuel.2018.03.056
Abstract: Abstract In this paper, a robust method based on solvent-volume controlled full evaporation headspace gas chromatography technique (FE HS-GC) was developed to high throughput quantify γ-valerolactone (GVL) concentration in sample solution. The results showed that… read more here.
Keywords: technique; content synthesis; determination valerolactone; valerolactone content ... See more keywords
Magnetic Fe3O4 nanoparticles and ZrO2-doped mesoporous MCM-41 as a monolithic multifunctional catalyst for γ-valerolactone production directly from furfural
Sign Up to like & getrecommendations! Published in 2021 at "Fuel"
DOI: 10.1016/j.fuel.2021.120996
Abstract: Abstract A magnetically-recoverable multifunctional catalyst (Fe3O4/ZrO2@MCM-41) was tailored by the impregnation of ZrO2 supported on mesoporous MCM-41 coated Fe3O4 nanoparticles, which successfully served as a monolithic catalyst for the cascade conversion of furfural (FAL) giving… read more here.
Keywords: mesoporous mcm; valerolactone; catalyst; fe3o4 ... See more keywords
Hydrogenation of levulinic acid to γ-valerolactone over bifunctional Ru/(AlO)(ZrO) catalyst: Effective control of Lewis acidity and surface synergy
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DOI: 10.1016/j.mcat.2020.111097
Abstract: Abstract A bifunctional Ru/(AlO)(ZrO)n catalyst was reported for efficient hydrogenation of levulinic acid to γ-valerolactone, an important and environmental-benign upgrading process of bio-platform compound. The optimal Ru/(AlO)(ZrO)0.1 catalyst showed 100% yield to γ-valerolactone in water… read more here.
Keywords: alo zro; catalyst; levulinic acid; acid ... See more keywords
Promoter Effect of Pt on Zr Catalysts to Increase the Conversion of Furfural to γ-Valerolactone Using Batch and Continuous Flow Reactors: Influence of the Way of the Incorporation of the Pt Sites
Sign Up to like & getrecommendations! Published in 2024 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.4c01174
Abstract: The valorization of biomass and its transformation into fuels are highly interesting due to the abundance of biomass and its almost neutral carbon emissions. In this article, we show the production of γ-valerolactone (GVL), a… read more here.
Keywords: reaction; batch continuous; effect; flow reactors ... See more keywords
Rational Optimization of Reaction Conditions for the One-Pot Transformation of Furfural to γ-Valerolactone over Zr–Al-Beta Zeolite: Toward the Efficient Utilization of Biomass
Sign Up to like & getrecommendations! Published in 2018 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.8b02475
Abstract: The optimization of the production of γ-valerolactone (GVL) from furfural (FAL) through a cascade of transformations involving hydrogen transfer and different acid-driven reactions has been tackled by using a bifunctional Zr–Al-beta zeolite as catalyst. The… read more here.
Keywords: beta zeolite; reaction conditions; optimization; reaction ... See more keywords
Well-Defined Poly(α-amino-δ-valerolactone) via Living Ring-Opening Polymerization
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DOI: 10.1021/acs.macromol.7b02489
Abstract: This article demonstrates the synthesis of a new kind of cationic poly(δ-valerolactone) with primary amino groups at α-positions (poly(α-NH2-VL)) via ring-opening polymerization (ROP) of α-NHBoc-valerolactone (α-NHB-VL) followed by a simple deprotection reaction. The ROP of… read more here.
Keywords: ring opening; amino; polymerization; opening polymerization ... See more keywords