Vanadium(V) Catalysts with High Activity for the Coupling of Epoxides and CO2: Characterization of a Putative Catalytic Intermediate
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DOI: 10.1021/acscatal.7b00109
Abstract: Vanadium(V) complexes derived from aminotriphenolate ligands are demonstrated to be highly active catalysts for the coupling of various terminal and internal epoxides with carbon dioxide to afford a series of substituted organic carbonates in good… read more here.
Keywords: vanadium catalysts; activity coupling; catalysts high; high activity ... See more keywords
Promotion of B(C6F5)3 as Ligand for Titanium (or Vanadium) Catalysts in the Copolymerization of Ethylene and 1-Hexene: A Computational Study
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DOI: 10.3390/polym15112435
Abstract: Density functional theory (DFT) is employed to investigate the promotion of B(C6F5)3 as a ligand for titanium (or vanadium) catalysts in ethylene/1-hexene copolymerization reactions. The results reveal that (I) Ethylene insertion into TiB (with B(C6F5)3… read more here.
Keywords: ethylene hexene; c6f5 ligand; titanium vanadium; vanadium catalysts ... See more keywords