Vanadium‐Catalyzed Deoxydehydration of Glycerol Without an External Reductant
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DOI: 10.1002/cctc.201701049
Abstract: A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was… read more here.
Keywords: glycerol; vanadium catalyzed; reductant; vanadium ... See more keywords
Vanadium-Catalyzed Dinitrogen Reduction to Ammonia via a [V]═NNH2 Intermediate.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08000
Abstract: The catalytic transformation of N2 to NH3 by transition metal complexes is of great interest and importance but has remained a challenge to date. Despite the essential role of vanadium in biological N2 fixation, well-defined… read more here.
Keywords: vanadium; vanadium catalyzed; catalyzed dinitrogen; reduction ... See more keywords
Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
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DOI: 10.1039/d0ra02503h
Abstract: A new synthetic method is described to construct 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed [2+2+1] cycloaddition reactions. Reactions of azobenzenes as nitrogen sources with phosphaalkynes as phosphorous counterparts in the presence of VCl2(thf)2 as a catalyst… read more here.
Keywords: azadiphosphole derivatives; cycloaddition reactions; based vanadium; catalyzed cycloaddition ... See more keywords