Role of Multiple Vanadium Centers on Redox Buffering and Rates of Polyvanadomolybdate-Cu(II)-Catalyzed Aerobic Oxidations
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DOI: 10.1021/acs.inorgchem.3c00469
Abstract: A recent report established that the tetrabutylammonium (TBA) salt of hexavanadopolymolybdate TBA4H5[PMo6V6O40] (PV6Mo6) serves as the redox buffer with Cu(II) as a co-catalyst for aerobic deodorization of thiols in acetonitrile. Here, we document the profound… read more here.
Keywords: role multiple; vanadium centers; vanadium; redox buffering ... See more keywords